CHAPTER 4: POLYMER

4.1 POLYMER

Natural polymers are polymers that are naturally available and can be obtained from our surroundings.

Examples of natural polymers are starch, protein and cotton

A polymer is a long chain molecule that is made from a combination of many repeating basic unit

Synthetic polymers, on the other hand, are man-made through chemical reactions in laboratories or factories.

Nylon, polyethene, polystyrene and polyvinyl chloride (PVC) are examples of synthetic polymers that are manufactured in the industrial sector

Types of Polymers

• Thermoplastic polymers are polymers that can be repeatedly remoulded upon heating and can be recycled.

• When heated, the thermoplastic polymers melt and solidify when they are cooled.

• Example: polyethene, polyvinyl chloride (PVC), nylon.

Thermoplastic polymers

-Thermosetting polymers cannot be remoulded after heating. 

-Thermosetting polymers normally disintegrate or burn upon heating and cannot be recycled

-Example: melamine, bakelite.

Thermoplastic polymers

Elastomer polymers can be stretched and can return to their original shape when released. 

• Possess high elasticity properties. 

• Example: polyurethane, styrene-butadiene rubber (SBR).

Thermosetting polymers

Polymerisation Reaction

1. Addition Polymerisation Addition polymerisation occurs when monomers that have double covalent bonds between two carbon atoms, C=C react with one another

2. Condensation polymerisation involves at least two different monomers.The monomers involved consist of two functional groups that will take part in the polymerisation reaction. The product of condensation polymerisation is a polymer and another by-product such as water or HCl molecule.